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Interplay between columnar and smectic stability in suspensions of polydisperse colloidal platelets

机译:悬浮液中柱状和近晶稳定性之间的相互作用   多分散胶体血小板

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摘要

The phase behavior of a model suspension of colloidal polydisperse plateletsis studied using density-functional theory. Platelets are modelled as parallelrectangular prisms of square section $l$ and height $h$, with length and heightdistributions given by different polydispersities $\delta_l$ and $\delta_h$. Weobtain the phase behavior of the model, including nematic, smectic and columnarphases and its dependence with the two polydispersities $\delta_l$ and$\delta_h$. When $\delta_l>\delta_h$ we observe that the smectic phasestabilises first with respect to the columnar. If $\delta_h>\delta_l$ weobserve the opposite behavior. Other more complicated cases occur, e.g. thesmectic stabilises from the nematic first but then exists a first-ordertransition to the columnar phase. Our model assumes plate-rod symmetry, but theregions of stability of smectic and columnar phases are non-symmetric in the$\delta_l-\delta_h$ plane due to the different dimensionality of ordering inthe two phases. Microsegregation effects, i.e. different spatial distributionfor different sizes within the periodic cell, take place in both phases.
机译:使用密度泛函理论研究胶体多分散血小板模型悬浮液的相行为。血小板被建模为正方形截面$ l $和高度$ h $的平行矩形棱柱,其长度和高度分布由不同的多分散度$ \ delta_l $和$ \ delta_h $给出。我们获得了模型的相行为,包括向列相,近晶相和柱状相,以及它与两个多分散度$ \ delta_1和$ \ delta_h $的依赖关系。当$ \ delta_l> \ delta_h $时,我们观察到近晶相相对于柱状体首先稳定。如果$ \ delta_h> \ delta_l $,则观察到相反的行为。发生其他更复杂的情况,例如分子簇首先从向列相稳定下来,但随后存在一阶过渡到柱状相。我们的模型假定板-杆对称,但是近晶相和柱状相的稳定性区域在$ \ delta_1-\ delta_h $平面中由于两个相序的维数不同而不对称。在两个阶段中都会发生微偏析效应,即周期性细胞内不同大小的不同空间分布。

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